✦ LIBER ✦

The Millimeter-Wave Rotational Spectrum of CF3CN in the Excited Vibrational Statesv8= 3 andv8= 4

✍ Scribed by Pil Ja Seo; John H. Carpenter; John G. Smith

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 384 KB
Volume: 184
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7338

No coin nor oath required. For personal study only.

✦ Synopsis

The millimeter-wave rotational spectra of the excited vibrational states £ 8 Å 3 and £ 8 Å 4 of the symmetric top species trifluoroacetonitrile, CF 3 CN, have been recorded for JЉ Å 19 to JЉ Å 22. The analysis indicates that the resonance found for CF 3 CCH is also present here, but that it is less important because the avoided crossing occurs at higher k values which are not observed in these spectra. The effective vibrational anharmonicity parameter, x ll , was determined as 9312(9) MHz for £ 8 Å 3. The almost linear variation of the rotational constants with £ 8 suggests that these behave as isolated vibrational states.

📜 SIMILAR VOLUMES

The Millimeter-Wave Rotational Spectrum

The Millimeter-Wave Rotational Spectrum of CF3CN in Excited Vibrational States

✍ John H. Carpenter; Masoud Motamedi; John G. Smith 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 315 KB

The millimeter-wave rotational spectra of the excited vibrational states £ 4 Å 1, £ 7 Å 1, and £ 8 Å 1 of the symmetric top species trifluoroacetonitrile, CF 3 CN, have been recorded and analyzed for JЉ Å 16 up to JЉ Å 32. The parameters obtained have been used to provide further information on the

The Millimeter-Wave Rotational Spectrum

The Millimeter-Wave Rotational Spectrum of CCl3CN in Excited Vibrational States

✍ Pil Ja Seo; John H. Carpenter; John G. Smith; Matthew J. Whitston; Gabriele Cazz 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 410 KB

The millimeter-wave rotational spectra of the two lowest excited degenerate vibrational states £ 7 Å 1 and £ 8 Å 1 of the symmetric top species trichloroacetonitrile, CCl 3 CN, have been recorded and assigned for JЉ Å 20 up to JЉ Å 74. The Coriolis constants z 7 Å 00.695 and z 8 Å 0.530 have been de

The Millimeter-Wave Rotational Spectrum

The Millimeter-Wave Rotational Spectrum of CF3CCH in the Excited Vibrational States v10 = 3 and v10 = 4

✍ J.H. Carpenter; M. Motamedi; J.G. Smith 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 477 KB

The millimeter-wave rotational spectra of the excited vibrational states \(v_{10}=3\) and \(v_{10}=4\) of the symmetric top species 3,3,3-trifluoropropyne (trifluoromethylacetylene), \(\mathrm{CF}_{3} \mathrm{CCH}\), have been recorded for \(J^{\prime \prime}=16\) up to \(J^{\prime \prime}=21\). The

Millimeter and Submillimeter-Wave Spectr

Millimeter and Submillimeter-Wave Spectrum of Hydrogen Peroxide in the Ground andv3= 1 Vibrational States

✍ Douglas T. Petkie; Thomas M. Goyette; Frank C. De Lucia; Paul Helminger; S.P. Be 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 281 KB

The first measurements of the millimeter-and submillimeter (mm/submm)-wave rotational-torsional transitions in the v 3 ϭ 1 ground torsional state (n ϭ 0) of hydrogen peroxide are reported. The 149 newly measured transitions extend from 72 to 623 GHz in frequency and up to J ϭ 32 and K a ϭ 3 in rotat

The Millimeter-Wave Spectrum of CF3C35Cl

The Millimeter-Wave Spectrum of CF3C35Cl237Cl in Its Ground State and the Vibrational Force Field of Trifluorotrichloroethane

✍ P.J. Seo; J.H. Carpenter; J.G. Smith 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 351 KB

The millimeter-wave rotational spectra of the ground state of the asymmetric-top species \(\mathrm{CF}_{3} \mathrm{C}^{35} \mathrm{Cl}_{2}{ }^{37} \mathrm{Cl}\) have been recorded and assigned for \(J^{\prime \prime}=30\) up to \(J^{\prime \prime}=55\) and analyzed to yield the following rotational