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The mobile-phase effects on stationary-phase properties in capillary supercritical fluid chromatography

✍ Scribed by Novotny, M. ;David, P.

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
417 KB
Volume
9
Category
Article
ISSN
0935-6304

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✦ Synopsis

A significant uptake of supercritical mobile phases into immobilized stationary phases has been observed. The phase swelling effect has been evaluated hydrodynamically for SE-30, SE-54, and cyanopropyl silicone phases with respect to the mobilephase density of supercritical butane, column temperature, and the presence of a polar retention moderator. Some kinetic and retention consequences of the swelling phenomena are discussed.

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