The microstructure of poly(cyclopentene) produced by polymerization of cyclopentene with homogeneous Ziegler-Natta catalysts
β Scribed by Collins, Scott; Kelly, W. Mark
- Book ID
- 120434746
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 640 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = Ξ·~5~βC~5~H~5~), as a model for olefin polymerization with homogeneous ZieglerβNatta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c
A~traet--Polymerizations of styrene and 2-vinylpyridine were undertaken with AIEh-VCI 4 as homogeneous catalyst, under several sets of conditions. Conversion was related to the formation time of the catalytic species. Relative crystallinity and average molecular weight for the polymers obtained at 2