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Enantioselectivity in the Regioirregular Placements and Regiospecificity in the Isospecific Polymerization of Propene with Homogeneous Ziegler-Natta Catalysts

โœ Scribed by Guerra, Gaetano; Cavallo, Luigi; Moscardi, Gilberto; Vacatello, Michele; Corradini, Paolo


Book ID
125951464
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
936 KB
Volume
116
Category
Article
ISSN
0002-7863

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Hydrogen activation in propene polymeriz
โœ John C. Chadwick; Arjen Miedema; Olof Sudmeijer ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 273 KB

## Abstract ^13^C NMR analysis of relatively lowโ€molecularโ€weight polypropylenes prepared using the catalyst system MgCl~2~/TiCl~4~/phthalate esterโ€AlEt~3~โ€external Lewis base has revealed the presence of up to around 20% butyl (__n__โ€Bu) chain ends, indicative of regioirregular (2,1โ€) monomer inse