The unimolecular decomposition of methyl nitrite in the temperature range 680-955 K and pressure range 0.64 to 2.0 atm has been studied in shock-tube experiments employing real-time absorption of CW CO laser radiation by the NO product. Computer kinetic modeling using a set of 23 reactions shows tha
The methyl nitrite decomposition flame
β Scribed by E.A. Arden; J. Powling
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- English
- Weight
- 782 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0010-2180
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Decomposition flames of isopropyl nitrate and n-propyl nitrate have been stabilized upon their liquid surfaces at atmospheric pressure. Temperature distributions and reaction .product distributions have been measured through the flame zones. Suggestions have been made concerning the earliest degrada
The mechanism for unimolecular fragmentation of the methyl nitrite radical cation, CH,ONO+, has been determined by mass spectrometric techniques applying deuterium and I80 labelling. It could be unambiguously concluded that methyl nitrite radical cations possessing low internal energy fragment exclu
## Abstract The reactions of O~3~ with CH~3~ONO and C~2~H~5~ONO were studied using infrared absorption spectroscopy in a static reactor at temperatures between 298 and 352K. Both reactions followed simple secondβorder kinetics forming the corresponding nitrate: equation image The rate coefficient