✦ LIBER ✦

Flame decomposition of the propyl nitrates

✍ Scribed by J. Powling; W.A.W. Smith

Publisher: Elsevier Science
Year: 1957
Tongue: English
Weight: 718 KB
Volume: 1
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(57)90017-2

No coin nor oath required. For personal study only.

✦ Synopsis

Decomposition flames of isopropyl nitrate and n-propyl nitrate have been stabilized upon their liquid surfaces at atmospheric pressure. Temperature distributions and reaction .product distributions have been measured through the flame zones. Suggestions have been made concerning the earliest degradation reactions giving rise to the many products observed in the flame front. The type of mechanism previously proposed for the ethyl nitrate flame degradation will describe quite adequately the appearance of practically all o¢ the many observed ingredients o] the propyl nitrate flames. The nitric ester is attacked by nitrogen dioxide and nitrous acid which abstract a methyl group or a hydrogen atom, leaving an unstable residue which breaks down spontaneously, with frequent regeneration of these active species to continue the chain.

📜 SIMILAR VOLUMES

Decomposition of nitrates by decompositi

Decomposition of nitrates by decomposition in the dark

✍ C. 📂 Article 📅 1881 🏛 Elsevier Science 🌐 English ⚖ 57 KB

## I)ecompositio~ of ±~5"trah,,~. 15:~ Applications of Electricity. --[t lms been sometimes thought that a copper cable of enormous thickness would be required to transmit the hydraulic power of Niagara fitlls to New Y()rk. Pro/: Aw-ton has shown that the whole power e()uhl be transmitted by a sle

The methyl nitrite decomposition flame

✍ E.A. Arden; J. Powling 📂 Article 📅 1958 🏛 Elsevier Science 🌐 English ⚖ 782 KB

The radiation induced decomposition of p

The radiation induced decomposition of potassium nitrate

✍ J. Forten; E.R. Johnson 📂 Article 📅 1960 🏛 Elsevier Science 🌐 English ⚖ 610 KB

Thermal decomposition of isooctyl nitrat

Thermal decomposition of isooctyl nitrate

✍ H.O. Pritchard 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 149 KB

Screening tests of sodium nitrate and po

Screening tests of sodium nitrate and potassium nitrate decomposition

✍ C.M. Kramer; Z.A. Munir; J.V. Volponi 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 266 KB

Very low-pressure pyrolysis. IV. The dec

Very low-pressure pyrolysis. IV. The decomposition of i-propyl iodide and n-propyl iodide

✍ Keith D. King; David M. Golden; G. Neil Spokes; Sidney W. Benson 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 584 KB

The decomposition rate constant of i-PrI under conditions of very low-pressure pyrolysis (VLPP) is completely consistent with the well-known high-pressure Arrhenius parameters and the RRK(M) theory. The decomposition of n-PrI under the same conditions proceeds via two pathways, the anti-Markownikoff