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The reactions of ozone with methyl and ethyl nitrites

✍ Scribed by D. R. Hastie; C. G. Freeman; M. J. McEwan; H. I. Schiff

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
263 KB
Volume
8
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The reactions of O~3~ with CH~3~ONO and C~2~H~5~ONO were studied using infrared absorption spectroscopy in a static reactor at temperatures between 298 and 352K. Both reactions followed simple second‐order kinetics forming the corresponding nitrate:

equation image

The rate coefficients are given by

.

πŸ“œ SIMILAR VOLUMES

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## Abstract The absolute rate constant for the reaction of methyl radicals with ozone has been measured as a function of temperature. Small concentrations of CH~3~ were generated by flash photolyzing CH~3~NO~2~ at 193 nm with an ArF laser. A photoionization mass spectrometer was used to follow the

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