The methoxy radical
β Scribed by J.T. Carter; D.B. Cook
- Book ID
- 113257276
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 799 KB
- Volume
- 251
- Category
- Article
- ISSN
- 0166-1280
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The addition of methoxy radicals to several olefins has been studied by a competitive method at 127Β°C in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon
## Abstract Using dimethyl peroxide as a thermal source of methoxy radicals overthe temperature range of 110β160Β°C, and the combination of methoxy radicals and nitrogen dioxide as a reference reaction: equation image a value was determined of the rate constant for the reaction of methoxy radicals
We report a kinetic study which indicates that the stabilizing effect of the methoxy group in a pure rsdieal system is small. The rates of d~com~s~tion of I (diphenyl ether, l.50Β° to 180Β° C) and II (toluene, 50' to 80' C) were monitored by measuring nitrogen evolution using a constsnt volume variab