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Substituent effects and free radical stability. The methoxy group

✍ Scribed by Jack W. Timberlake; Melvin L. Hodges

Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 312 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)98689-7

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✦ Synopsis

We report a kinetic study which indicates that the stabilizing effect of the methoxy group in a pure rsdieal system is small.

The rates of d~com~s~tion of I (diphenyl ether, l.50° to 180° C) and II (toluene, 50' to 80' C) were monitored by measuring nitrogen evolution using a constsnt volume variable pressure kinetic apparatus.

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