The mechanism of thermal eliminations. Part 16. Rate data for pyrolysis of 2-(2-hydroxyethyl)pyridine; prediction of elimination rates
โ Scribed by Taylor, Roger
- Book ID
- 115459654
- Publisher
- Royal Society of Chemistry
- Year
- 1983
- Tongue
- English
- Weight
- 378 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1472-779X
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๐ SIMILAR VOLUMES
## The first-order rate constants of N-acetyl-Nะ-phenylthiourea (1), N-benzoyl-Nะ-phenyl-(2a), N-benzoyl-Nะ-(4-nitrophenyl)-(2b), N-benzoyl-Nะ-(3-chlorophenyl) (2c), N-benzoyl-Nะ-(4-chlorophenyl) (2d), and N-benzoyl-Nะ-(4-methylphenyl)thiourea (2e) were measured between 423 and 500 K. The reaction
Rates of thermal decomposition of N-acetylurea (l), N-acetylthiourea (2), N,N'-diacetylthiourea (3), and N-acetylthiobenzamide (4) have been measured over a 45 K range for each compound. The molecules were found to undergo unimolecular first-order elimination reactions for which log A = 11. 9, 11.6,