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The thermal degradation of polyvinyl acetate. Part 2.?Determination of the rate constants of the primary processes involved in the elimination of acetic acid

โœ Scribed by Grassie, N.

Book ID
118172622
Publisher
Royal Society of Chemistry
Year
1953
Weight
481 KB
Volume
49
Category
Article
ISSN
0014-7672

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Effect of solvent on the rate constants
Effect of solvent on the rate constants in solution polymerization. Part II. Vinyl acetate
โœ Timothy F. Mckenna; A. Villanueva ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 256 KB ๐Ÿ‘ 2 views

Measurements were made of the value of the lumped kinetic constant k p /k t 0.5 of vinyl acetate in different solvents and with different initiators. This quantity was evaluated using the well-known conversion vs. time approach in dilute solutions using both azo-bis-isobutyronitrile and benzoyl pero