The mechanisms of thermal eliminations. Part 11. Rate data for pyrolysis of 2-alkoxypyridines to 2-pyridone, and of 2-ethoxypicolines to 2-picolones: nature and polarity of the transition state
β Scribed by Al-Awadi, Nouria; Ballam, John; Hemblade, Paul R.; Taylor, Roger
- Book ID
- 111965896
- Publisher
- Royal Society of Chemistry
- Year
- 1982
- Tongue
- English
- Weight
- 419 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
## The first-order rate constants of N-acetyl-NΠ-phenylthiourea (1), N-benzoyl-NΠ-phenyl-(2a), N-benzoyl-NΠ-(4-nitrophenyl)-(2b), N-benzoyl-NΠ-(3-chlorophenyl) (2c), N-benzoyl-NΠ-(4-chlorophenyl) (2d), and N-benzoyl-NΠ-(4-methylphenyl)thiourea (2e) were measured between 423 and 500 K. The reaction
Rate constants are reported for the state-specific vibrational relaxation of O2 (8 d v< 11) by NOz and O2 at 295 K. O2 is formed in vibrational levels up to II= 11 by the reaction of 0( 3P) atoms with NO1. The oxygen atoms were created by partial photolysis of NOz at 355 nm using a frequency-tripled