The Mechanism of the Wettstein-Oppenauer Oxidation
โ Scribed by Mandell, Leon
- Book ID
- 118025040
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 353 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
An alcohol oxidation process using an air-stable iron tricarbonyl compound structurally similar to Shvo's diruthenium bridging hydride was developed. Secondary benzylic and allylic alcohols are oxidized in high yields, and evidence for an Oppenauer-type mechanism is presented.
A detailed investigation of the mechanism of cyanogen oxidation is presented. Recent induction time measurements of ignition in cyanogen-xygen-argon mixtures behind reflected shocks are computer modeled to obtain an agreement between the experimental and calculated values. A 15-step reaction scheme