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The Oppenauer Oxidation of Steroid Semicarbazones

✍ Scribed by Gleason, Clarence H.; Holden, George W.

Book ID
126679892
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
252 KB
Volume
72
Category
Article
ISSN
0002-7863

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## Abstract A (hydroxycyclopentadienyl)iron dicarbonyl hydride catalyzes the Oppenauer‐type oxidation of alcohols with acetone as the hydrogen acceptor. Many functional groups are tolerant to the oxidation conditions. The same complex also catalyzes the dehydrogenation of diols to lactones. A mecha