𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Air-stable iron catalyst for the Oppenauer-type oxidation of alcohols

✍ Scribed by Sara A. Moyer; Timothy W. Funk

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
440 KB
Volume
51
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

An alcohol oxidation process using an air-stable iron tricarbonyl compound structurally similar to Shvo's diruthenium bridging hydride was developed. Secondary benzylic and allylic alcohols are oxidized in high yields, and evidence for an Oppenauer-type mechanism is presented.

πŸ“œ SIMILAR VOLUMES

Iron-Catalyzed Oppenauer-Type Oxidation
Iron-Catalyzed Oppenauer-Type Oxidation of Alcohols
✍ Michaelβ€…G. Coleman; Alecβ€…N. Brown; Brettβ€…A. Bolton; Hairong Guan πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 176 KB πŸ‘ 1 views

## Abstract A (hydroxycyclopentadienyl)iron dicarbonyl hydride catalyzes the Oppenauer‐type oxidation of alcohols with acetone as the hydrogen acceptor. Many functional groups are tolerant to the oxidation conditions. The same complex also catalyzes the dehydrogenation of diols to lactones. A mecha

First example of water-soluble transitio
First example of water-soluble transition-metal catalysts for Oppenauer-type oxidation of secondary alcohols
✍ Abdelaziz Nait Ajjou πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 53 KB

The first water-soluble transition-metal catalysts for Oppenauer-type oxidation of secondary alcohols have been developed. The catalytic system composed of [Ir(COD)Cl] 2 , 2,2%-biquinoline-4,4%-dicarboxylic acid dipotassium salt (BQC) and sodium carbonate is highly efficient for the selective oxidat