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The mechanism of the Wacker process. Corroborative evidence for distal addition of water and palladium

โœ Scribed by Akermark, Bjoern.; Soederberg, Bjoern C.; Hall, Stan S.


Book ID
125518093
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
432 KB
Volume
6
Category
Article
ISSN
0276-7333

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Palladium assisted alkylation of olefins under mild conditions is of current synthetic interest.l-' The cis mode of the addition of palladium and methyl or aryl anions to both cyclic and acyclic olefins was well documented, 2,3 while the stereochemical study of the carbopalladation using "stabilized