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Stereochemistry of the hydroxypalladation of ethylene. Evidence for trans addition in the wacker process

✍ Scribed by Stille, J. K.; Divakaruni, R.

Book ID
126177152
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
287 KB
Volume
100
Category
Article
ISSN
0002-7863

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Palladium assisted alkylation of olefins under mild conditions is of current synthetic interest.l-' The cis mode of the addition of palladium and methyl or aryl anions to both cyclic and acyclic olefins was well documented, 2,3 while the stereochemical study of the carbopalladation using "stabilized