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Rate and Mechanism of Oxidative Addition of Aryl Triflates to Zerovalent Palladium Complexes. Evidence for the Formation of Cationic (.sigma.-Aryl)palladium Complexes

✍ Scribed by Jutand, Anny; Mosleh, Adil

Book ID
120930304
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
929 KB
Volume
14
Category
Article
ISSN
0276-7333

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Mechanism of the oxidative addition of a
Mechanism of the oxidative addition of aryl halides to bis-carbene palladium(0) complexes
✍ Jutand, Anny (author);Pytkowicz, Julien (author);Roland, Sylvain (author);Mangen πŸ“‚ Article πŸ“… 2010 πŸ› Walter de Gruyter GmbH 🌐 English βš– 400 KB

Bis-__N__-heterocyclic carbenes Pd^0^ complexes, Pd^0^(NHC)~2~, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd^0^(NHC)~2~ that are not stable are generated in situ from Pd^II^ precursors PdY~2~(NHC)~2~ (Y = halides) after a chemical reduction. The latter