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Rate and Mechanism of the Oxidative Addition of Vinyl Triflates and Halides to Palladium(0) Complexes in DMF

✍ Scribed by Jutand, Anny; Négri, Serge

Book ID
127370104
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
172 KB
Volume
22
Category
Article
ISSN
0276-7333

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Bis-__N__-heterocyclic carbenes Pd^0^ complexes, Pd^0^(NHC)~2~, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd^0^(NHC)~2~ that are not stable are generated in situ from Pd^II^ precursors PdY~2~(NHC)~2~ (Y = halides) after a chemical reduction. The latter