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ChemInform Abstract: Mechanism of the Oxidative Addition of Aryl Halides to Bis-Carbene Palladium(0) Complexes

✍ Scribed by Anny Jutand; Julien Pytkowicz; Sylvain Roland; Pierre Mangeney

Publisher
John Wiley and Sons
Year
2010
Weight
20 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Rate and Mechanism of the Reversible For
Rate and Mechanism of the Reversible Formation of Cationic (Ξ·3-Allyl)- palladium Complexes in the Oxidative Addition of Allylic Acetate to Palladium(0) Complexes Ligated by Diphosphanes
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The oxidative addition of the allylic acetate, CH 2 CH Γ€ CH 2 Γ€ OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h