✦ LIBER ✦

The mechanism of the regioselective reduction of quinoline catalyzed by [RuH(CO)(NCMe)2(PR3)2]BF4: a theoretical investigation

✍ Scribed by Merlin Rosales; Mirixa Boves; Humberto Soscún; Fernando Ruette

Book ID: 114142977
Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 212 KB
Volume: 433
Category: Article
ISSN: 0166-1280
DOI: 10.1016/s0166-1280(98)00037-2

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics and mechanisms of homogeneous c

Kinetics and mechanisms of homogeneous catalytic reactions. Part 3. Regioselective, catalysed [RuH(CO)(NCMe)2(PPh3)2]BF4reduction of quinoline

✍ Merlin Rosales; Ysaías Alvarado; Mirixa Boves; Raúl Rubio; Humberto Soscún; Robe 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 551 KB

A kinetic study of the regioselective homogeneous hydrogenation of quinoline (Q) to 1,2,3,4-tetrahydroquinoline (THQ) was carried out using the cationic complex I-RuH-(CO)(NCMe)2(PPh3)2]BF4 (1) as the precatalyst. The experimentally determined rate law was r = {k2Kj(1 s-1 at 398 K). The correspondi

Kinetics and mechanisms of homogeneous c

Kinetics and mechanisms of homogeneous catalytic reactions: Part 1. Hydrogenation of benzaldehyde catalyzed by [RuH(CO)(NCMe)2(PPh3)2]BF4

✍ Merlin Rosales; Angel González; Ysaias Alvarado; Raúl Rubio; Antida Andriollo; R 📂 Article 📅 1992 🏛 Elsevier Science ⚖ 708 KB

Theoretical investigation on regioselect

Theoretical investigation on regioselectivity of aromatic ketones in the addition with olefin catalyzed by RuH2(CO)(PPh3)3

✍ Ming Lei; Wenlin Feng; Hongguang Du; Zhenfeng Xu 📂 Article 📅 2000 🏛 SP Science China Press 🌐 English ⚖ 198 KB

Kinetics and mechanisms of homogeneous c

Kinetics and mechanisms of homogeneous catalytic reactions. Part 5. Regioselective reduction of heteroaromatic nitrogen compounds catalysed by [OsH(CO)(NCMe)2(PPh3)2]BF4

✍ Merlin Rosales; Jéssica Castillo; Angel González; Larry González; Karely Molina; 📂 Article 📅 2004 🏛 Springer 🌐 English ⚖ 141 KB

Kinetic and mechanistic investigation of

Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by OsHCl(CO)(PR3)2 [PR3 = PMe-tert-Bu2 and P-i-Pr3]

✍ Andriollo, Antida; Esteruelas, Miguel A.; Meyer, Uwe; Oro, Luis A.; Sanchez-Delg 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 874 KB

Kinetics and mechanisms of homogeneous c

Kinetics and mechanisms of homogeneous catalytic reactions. Part 4. Hydrogenation of cyclohexanone and 2-cyclohexen-1-one catalysed by the complexes [MH(CO)(NCMe)2(PPh3)2]BF4(M = Ru, Os)

✍ Merlin Rosales; Ángel González; Milagros Mora; Nidal Nader; Janeth Navarro; Ligb 📂 Article 📅 2004 🏛 Springer 🌐 English ⚖ 111 KB