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Kinetics and mechanisms of homogeneous catalytic reactions. Part 4. Hydrogenation of cyclohexanone and 2-cyclohexen-1-one catalysed by the complexes [MH(CO)(NCMe)2(PPh3)2]BF4(M = Ru, Os)

✍ Scribed by Merlin Rosales; Ángel González; Milagros Mora; Nidal Nader; Janeth Navarro; Ligbel Sánchez; Humberto Soscún


Book ID
111613542
Publisher
Springer
Year
2004
Tongue
English
Weight
111 KB
Volume
29
Category
Article
ISSN
0340-4285

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Kinetics and mechanisms of homogeneous c
✍ Merlin Rosales; Ysaías Alvarado; Mirixa Boves; Raúl Rubio; Humberto Soscún; Robe 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 551 KB

A kinetic study of the regioselective homogeneous hydrogenation of quinoline (Q) to 1,2,3,4-tetrahydroquinoline (THQ) was carried out using the cationic complex I-RuH-(CO)(NCMe)2(PPh3)2]BF4 (1) as the precatalyst. The experimentally determined rate law was r = {k2Kj(1 s-1 at 398 K). The correspondi