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Synthesis, characterization and some catalytic properties of ruthenium complexes Ru(PPh3)2Cl2(L)2 [L = 4-But-py, 4-vinyl-py, 4-CN-py, 4-Me-py, 3-Me-py, L2 = 4,4′-bipy]. Kinetics of cyclohexene hydrogenation catalysed by Ru(PPh3)2Cl2(4-But-py)2

✍ Scribed by E. Argüello; A. Bolaños; F. Cuenu; M. Navarro; V. Herrera; A. Fuentes; R.A. Sanchez-Delgado

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
496 KB
Volume
15
Category
Article
ISSN
0277-5387

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📜 SIMILAR VOLUMES

Inert and Labile [Ru(L)(‘pyS4’)] Complex
Inert and Labile [Ru(L)(‘pyS4’)] Complexes with Rigid [RuNS4] Cores and trans-Thiolate Donors [L = PPh3, PEt3, DMSO, CO, NO+, N2H4; ‘pyS4’2– = 2,6-Bis(2-mercaptophenylthio)dimethylpyridine(2–)]
✍ Dieter Sellmann; Klaus Engl; Frank W. Heinemann 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 311 KB 👁 1 views

In a quest for ruthenium complexes having [RuNS 4 ] cores, a non-fluxional configuration, trans-thiolate donors, and exchangeable coligands L, [Ru(L)('pyS 4 ')] complexes have been synthesized 1). Alkylation of 1 with excess MeI yielded [Ru(PPh 3 )('pyS 4 '-Me 2 )]I 2 (2). [Ru(DMSO)('pyS 4 ')] (3) w