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Ruthenium Cationic Species for Transfer Hydrogenation of Aldehydes: Synthesis and Catalytic Properties of [(PPh3)2Ru(CH3CN)3Cl] +[A]- {A = BPh4 or ClO4} and Structure of [(PPh3)2Ru(CH3CN)3Cl] +[BPh4]-.

✍ Scribed by Sipra Naskar; Manish Bhattacharjee


Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure