Syntheses, Crystal Structures and Optical Limiting Properties of Three Novel Organometallic Tungsten-Copper-Sulfur Clusters: [PPh4][(η5-C5Me5)WS3(CuCN)2], [(η5-C5Me5)WS3Cu2(PPh3)(μ-CN)]2 and [PPh4][{(η5-C5Me5)WS3Cu2(CN)(Py)}2(μ-CN)]
✍ Scribed by Jian-Ping Lang; Qing-Feng Xu; Wei Ji; Hendry Izaac Elim; Kazuyuki Tatsumi
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 171 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3
Organometallic Compounds of the Lanthanoids. Part 129. Synthesis, Structure and Hydrolysis of "Moderately Stable" Hydrosilylation Catalysts [(η 5 -C 5 H 4 SiMe 3 ) 2 Ln(µ-Me
Two new 1,2,3,5-dithiadiazoles, [4-(4Ј-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Ј-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t