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Kinetics and mechanisms of homogeneous catalytic reactions. Part 5. Regioselective reduction of heteroaromatic nitrogen compounds catalysed by [OsH(CO)(NCMe)2(PPh3)2]BF4

✍ Scribed by Merlin Rosales; Jéssica Castillo; Angel González; Larry González; Karely Molina; Janeth Navarro; Inés Pacheco; Homero Pérez

Book ID
111613545
Publisher
Springer
Year
2004
Tongue
English
Weight
141 KB
Volume
29
Category
Article
ISSN
0340-4285

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Kinetics and mechanisms of homogeneous c
Kinetics and mechanisms of homogeneous catalytic reactions. Part 3. Regioselective, catalysed [RuH(CO)(NCMe)2(PPh3)2]BF4reduction of quinoline
✍ Merlin Rosales; Ysaías Alvarado; Mirixa Boves; Raúl Rubio; Humberto Soscún; Robe 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 551 KB

A kinetic study of the regioselective homogeneous hydrogenation of quinoline (Q) to 1,2,3,4-tetrahydroquinoline (THQ) was carried out using the cationic complex I-RuH-(CO)(NCMe)2(PPh3)2]BF4 (1) as the precatalyst. The experimentally determined rate law was r = {k2Kj(1 s-1 at 398 K). The correspondi