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Kinetics and mechanisms of homogeneous catalytic reactions. Part 8. Regioselective reduction of benzo[b]thiophene catalyzed by OsH(CO)(κ3-OCOCH3)(PPh3)2

✍ Scribed by Rosales, Merlín ;Gonzálezóz, Ángel ;Hernández, Alicia ;Pacheco, Inés ;Salazar, Yslamar


Book ID
106512754
Publisher
Springer
Year
2007
Tongue
English
Weight
134 KB
Volume
92
Category
Article
ISSN
0133-1736

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Kinetics and mechanisms of homogeneous c
✍ Merlin Rosales; Ysaías Alvarado; Mirixa Boves; Raúl Rubio; Humberto Soscún; Robe 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 551 KB

A kinetic study of the regioselective homogeneous hydrogenation of quinoline (Q) to 1,2,3,4-tetrahydroquinoline (THQ) was carried out using the cationic complex I-RuH-(CO)(NCMe)2(PPh3)2]BF4 (1) as the precatalyst. The experimentally determined rate law was r = {k2Kj(1 s-1 at 398 K). The correspondi