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The mechanism of the reduction of α,β-unsaturated (steroid) ketones with diborane

✍ Scribed by Ian Midgley; Carl Djerassi

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 130 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94396-5

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✦ Synopsis

Caglioti and coworkers have shown that certain a&unsaturated ketones react with excess diborane, and after hydrolysis of the organoborane intermediate with acetic anhydride, good yields of an alkene are obtained. 192 The reaction undoubtedly follows the course depicted in the Scheme: Scheme

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