The mechanism of the reduction of pyridinium ions by sodium borohydride, II.
โ Scribed by Paul S. Anderson; Robert E. Lyle
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 199 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The reaction between BH4and CH20 has been investigated in the gas phase using ion cyclotron resonance spectroscopy. MO hydride transfer from
Acetone, acetophenone and benzophenone react with sodium borohydride in the absence of protic solvent to give the corresponding tetraalkoxyborates. In view of these res-ults, the possibility of the 4-centre mechanism for these reductions is discussed.
A kinetic investigation has been carried out on the reduction of some aromatic ketones (acetophenone, 1;2-methoxyacetophenone, 2; 3-methoxyacetophenone, 3; 4-methoxyacetophenone, \(4 ;\) and \(\alpha\)-tetralone, 5 ) by sodium borohydride in the presence of two cationic surfactants (cetyltrimethylam