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The mechanism of the reduction of pyridinium ions by sodium borohydride, II.

โœ Scribed by Paul S. Anderson; Robert E. Lyle


Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
199 KB
Volume
5
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Reduction of ketones by sodium borohydri
โœ Margaret M. Kayser; Sonia Eliev; Odile Eisenstein ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

Acetone, acetophenone and benzophenone react with sodium borohydride in the absence of protic solvent to give the corresponding tetraalkoxyborates. In view of these res-ults, the possibility of the 4-centre mechanism for these reductions is discussed.

Reduction of Ketones by Sodium Borohydri
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A kinetic investigation has been carried out on the reduction of some aromatic ketones (acetophenone, 1;2-methoxyacetophenone, 2; 3-methoxyacetophenone, 3; 4-methoxyacetophenone, \(4 ;\) and \(\alpha\)-tetralone, 5 ) by sodium borohydride in the presence of two cationic surfactants (cetyltrimethylam