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The mechanism of borohydride reductions. Reactions of gas phase borohydride ion with carbonyl groups by ion cyclotron resonance spectroscopy.

✍ Scribed by M.M. Kayser; T.B. McMahon


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
204 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reaction between BH4and CH20 has been investigated in the gas phase using ion cyclotron resonance spectroscopy. MO hydride transfer from


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The gas-phase reactions of the O -β€’ radical anion with the halomethanes CH 3 X, CH 2 X 2 , CHX 3 , CX 4 , CF 3 X, CF 2 X 2 , CFX 3 (X = Br and Cl) and CXClBr 2 (X = Cl and F) have been examined at a low pressure (10 -5 -10 -4 Pa) with use of Fourier transform ion cyclotron resonance (FTICR) mass spe