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Reduction of ketones by sodium borohydride in the absence of protic solvents. Inter versus intramolecular mechanism

✍ Scribed by Margaret M. Kayser; Sonia Eliev; Odile Eisenstein


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
207 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


Acetone, acetophenone and benzophenone react with sodium borohydride in the absence of protic solvent to give the corresponding tetraalkoxyborates.

In view of these res-ults, the possibility of the 4-centre mechanism for these reductions is discussed.


πŸ“œ SIMILAR VOLUMES


Reduction of Ketones by Sodium Borohydri
✍ Giorgio Cerichelli; Marcello Coreno; Giovanna Mancini πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 348 KB

A kinetic investigation has been carried out on the reduction of some aromatic ketones (acetophenone, 1;2-methoxyacetophenone, 2; 3-methoxyacetophenone, 3; 4-methoxyacetophenone, \(4 ;\) and \(\alpha\)-tetralone, 5 ) by sodium borohydride in the presence of two cationic surfactants (cetyltrimethylam

ChemInform Abstract: Reductive Amination
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