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THE MECHANISM OF THE REACTION BETWEEN LITHIUM N-BUTYL AND VARIOUS ORGANIC HALOGEN COMPOUNDS

✍ Scribed by Marvel, C. S.; Hager, F. D.; Coffman, D. D.


Book ID
127203353
Publisher
American Chemical Society
Year
1927
Tongue
English
Weight
388 KB
Volume
49
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Addition and metallation in the reaction
✍ D.J. Booth; B.W. Rockett πŸ“‚ Article πŸ“… 1967 πŸ› Elsevier Science 🌐 French βš– 196 KB

A number of N,N-dialhylarylmethylamiues including beasyldimethylamine (2), dimethylaminomethylferrocene (I), (3), N-(ferrocenylmethyl)piperidine (4), and N-(ferrocenylmethyl)pyrrolidine (4), have been shown to undergo specific 2-lithiation by n-butyl-lithium in ether-herane. Thus the amine (I) gave