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Reaction mechanism and pathway for the hydrothermal electrolysis of organic compounds

✍ Scribed by Mitsuru Sasaki; Kana Yamamoto; Motonobu Goto

Publisher
Springer
Year
2007
Tongue
English
Weight
417 KB
Volume
9
Category
Article
ISSN
1438-4957

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Reactions of cyclopalladated compounds a
Reactions of cyclopalladated compounds and alkynes: New pathways for organic synthesis?
✍ Michel Pfeffer πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 919 KB

## Abstract Cyclometallated compounds, obtained by direct intramolecular C–H activation of a ligand by transition metals, are fairly reactive [especially those derived from palladium(II)] towards insertion of internal alkynes into their metal‐carbon bond. This reaction leads to either new organomet