Laser-induced excitation spectra of the two bands a ˜3B 1 -X ˜1A 1 , 2 0 1 and 1 0 1 of 32 SO 2 and 34 SO 2 have been recorded in a supersonic jet at a resolution of 0.015 cm Ϫ1 . The rotational and electron-spin fine structure has been analyzed for both isotopic species. Analysis of the rotational
The mechanism of the photochemical reactions of SO2 with C2H2 and CO excited within the SO2(3B1) ← SO2(X̃1A1) “forbidden” band
✍ Scribed by Fu Su; Jack G. Calvert
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 464 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Two assignments for the 3B ,-X 'A I band system of SO, are presented. Vibrational constants for the triplet state are calculated for both assignments. It is shown that both assignments are consistent with existing experimental information on band locations, band intensities, and isotopic shift data.
Quantum yield measurements for the S02(3B1) photosensitized isomerization of cis-1,2-diflu%roethylene have been made at 3712 A and 22°C. The ## [ S O ~] / [ C ~T -C ~F ~H Z ] ratio was varied from 47.4 to 455 and the quantum yield measurements over this variation of concentration ratios were consi
The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma