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The Mechanism of the Lithium Ethoxide Induced Conversion of N-Nitroso-N-(2,2-diphenylcyclopropyl)urea to 2,2-Diphenyldiazocyclopropane 1

โœ Scribed by Jones, W. M.; Muck, D. L.; Tandy, T. K.

Book ID
126917438
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
945 KB
Volume
88
Category
Article
ISSN
0002-7863

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Cyclopropylidene: the origin of 1,1-diph
Cyclopropylidene: the origin of 1,1-diphenylallene in the reaction of N-Nitroso-N-(2,2-diphenyl)cyclopropyl urea with lithium ethoxide
โœ W.M. Jones; Michael H. Grasley ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 255 KB

IN the course of an examination of the reaction of N-nitroso-N-(2,2-diphenyl)-cyclopropyl urea (I) with lithium ethoxide we have observed as the predominant product 1,1-diphenylallene. This observation was certainly not N=O 0 ' W. von E. Doering and P.M. 1 LaFlamme, Tetrahedron 1, 75 (1958).