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Oxidation of nitrosamines. 2. Conversion of N-nitroso-1,2,3,6-tetrahydropyridine, via the epoxide, to N-nitroso-4-hydroxy-1,2,3,4-tetrahydropyridine

✍ Scribed by Saavedra, Jose E.


Book ID
120301533
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
394 KB
Volume
44
Category
Article
ISSN
0022-3263

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Synthesis of 1,2-Dihydropyridines, 2,3-D
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## Abstract New procedures are described for the synthesis of Ξ±,β‐ethylenic and acetylenic aldehydes from 2‐butene‐ and 2‐butyne‐1,4‐diol, respectively (see __Scheme 1__). These are applied to the preparation of a particular δ‐acetylamino‐α,β‐ethylenic aldehyde ((__E__)‐**5**) as well as of its ace