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The Base-Catalyzed Decomposition of N-Nitroso-N-cyclohexylurethan 1,2

โœ Scribed by Bollinger, Frederick W.; Hayes, F. N.; Siegel, Samuel


Book ID
127039503
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
377 KB
Volume
72
Category
Article
ISSN
0002-7863

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The base-induced decomposition of N-nitr
โœ Sidney M. Hecht; John W. Kozarich ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 245 KB

To date three mechanisms have been proposed for the base-induced decomposition of N-nitroso-N-alkylureas. A mechanism involving initial nucleophilic attack on the carbonyl moiety of the urea (Scheme I) had been assumed 1\*2 to be correct, by analogy with the