Table 1. Side-chain alkylation of toluene with ethylene. Cr-Ni-Mo steel autoclave (314 cm'), 20 g (217 mmol) toluene, 7 g (250 mmol) ethylene. 380 C. 55 atm, 2 h. C , H,CH,Br Toluene Yield [mol-";,I all straight [ w1:y J conversion n-propyi-,~-pentyl-chain alkyl-C%1 benzene benzene benzenes
✦ LIBER ✦
The mechanism of the bischler-napieralski reaction
✍ Scribed by Sreeramulu Nagubandi; G. Fodor
- Book ID
- 112126197
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1980
- Tongue
- English
- Weight
- 443 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0022-152X
No coin nor oath required. For personal study only.
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Ethylene ketals of the type (I) cyclise in presence of phosphorus pentoxide in pyrid& to give the ketal (II) which on hydrolysis yields l-phenyl-6:7-dimethoxy4oxo-3:4-dihydroisquinob (III). 1-(4-oxo-cyclohexyl)-6:7-dimethoxy-3:4-dihydroisoquinoline (Vlll) and 2-oxo-3-methyl-g:1& dimethoxy-I 2:3:4:6: