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The mechanism of the addition of haloalkanes to alkenes in the presence of [RuH3(SiMe2Ph)(PPh3)3] and [RuH2(PPh3)4]

✍ Scribed by Reg Davis; John D. Furze; David J. Cole-Hamilton


Book ID
103229172
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
343 KB
Volume
440
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES


Kinetics and mechanisms of homogeneous c
✍ Merlin Rosales; YsaΓ­as Alvarado; Mirixa Boves; RaΓΊl Rubio; Humberto SoscΓΊn; Robe πŸ“‚ Article πŸ“… 1995 πŸ› Springer 🌐 English βš– 551 KB

A kinetic study of the regioselective homogeneous hydrogenation of quinoline (Q) to 1,2,3,4-tetrahydroquinoline (THQ) was carried out using the cationic complex I-RuH-(CO)(NCMe)2(PPh3)2]BF4 (1) as the precatalyst. The experimentally determined rate law was r = {k2Kj(1 s-1 at 398 K). The correspondi