[Co4(μ3-As)3)(μ3,η3-As3)(PPh3)4], a Product of the Reaction of [CoCl2(PPh3)2] with PhAs(SiMe3)2
✍ Scribed by Prof. Dr. Dieter Fenske; Dipl.-Chem. Johannes Hachgenei
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 358 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d