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Diphenylphosphido complexes of the lanthanides: reactions of compounds [Ln{N(SiMe3)2}3](Ln = La or Eu) or [Ln{N(SiMe3)2}3(Ph3PO)](Ln = La, Eu, or Y) with Ph2PH to give [Ln{N(SiMe3)2}2(PPh2)] or [Ln{N(SiMe3)2}2(PPh2)(Ph3PO)]

✍ Scribed by Aspinall, Helen C.; Bradley, Donald C.; Sales, Keith D.


Book ID
111965128
Publisher
The Royal Society of Chemistry
Year
1988
Tongue
English
Weight
384 KB
Volume
8
Category
Article
ISSN
1472-7773

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Synthese und Kristallstrukturen der Natr
✍ Marc Karl; Klaus Harms; Kurt Dehnicke πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 89 KB πŸ‘ 1 views

The title compounds as well as the corresponding scandium complex have been prepared from Ln[N(SiMe 3 ) 2 ] 3 (Ln = Sc, Gd, Yb), NaN(SiMe 3 ) 2 , and HNPh 2 in THF solution. They form colourless, moisture sensitive crystals of which the complexes with Ln = Gd (2) and Yb (3) were characterized by cry