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The Mechanism of Strong-Base-Initiated Polymerization of N-Carboxyanhydrides

โœ Scribed by Goodman, Murray.; Arnon, Uriel.


Book ID
127292416
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
868 KB
Volume
86
Category
Article
ISSN
0002-7863

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Solvent effects in N-carboxyanhydride (N
โœ A. Cosani; G. D'este; E. Peggion; E. Scoefone ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 251 KB

The 7-benzyl-cglutamate N-carboxyanhydride (NCA) polymerization initiated by diisopropylamine was studied in dimethylformamide (DMFWioxane mixtures of different compositions. It was found that the shape of the conversion versus time plots and the molecular weights of the polymers depend on the solve