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The initial reaction in strong-base catalyzed polymerizations of α-amino acid N-carboxyanhydrides

✍ Scribed by Murray Goodman; Uriel Arnon


Publisher
Wiley (John Wiley & Sons)
Year
1963
Tongue
English
Weight
209 KB
Volume
1
Category
Article
ISSN
0006-3525

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Polymerization of N-carboxyanhydrides of
✍ Yukio Imanishi; Akimasa Aoyama; Yutaka Hashimoto; Toshinobu Higashimura 📂 Article 📅 1977 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 494 KB

## Abstract In the polymerizations of alanine, γ‐ethyl glutamate, and leucine __N__‐carboxyanhydrides (NCA's) initiated by tertiary amines and some secondary amines such as __N__‐methyl‐L‐alanine dialkylamide, a stereoselectivity was observed: the polymerization rates of L‐ and D‐NCA's were identic