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Propagation Mechanism in Strong Base Initiated Polymerization of α-Amino Acid N-Carboxyanhydrides

✍ Scribed by Goodman, Murray; Hutchison, John


Book ID
126210483
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
260 KB
Volume
87
Category
Article
ISSN
0002-7863

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Polymerization of N-carboxyanhydrides of
✍ Yukio Imanishi; Akimasa Aoyama; Yutaka Hashimoto; Toshinobu Higashimura 📂 Article 📅 1977 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 494 KB 👁 1 views

## Abstract In the polymerizations of alanine, γ‐ethyl glutamate, and leucine __N__‐carboxyanhydrides (NCA's) initiated by tertiary amines and some secondary amines such as __N__‐methyl‐L‐alanine dialkylamide, a stereoselectivity was observed: the polymerization rates of L‐ and D‐NCA's were identic