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The mechanism of N2(B3Πg) deactivation by N2

✍ Scribed by A.M. Pravilov; L.G. Smirnova; A.F. Vilesov

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
336 KB
Volume
144
Category
Article
ISSN
0009-2614

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✦ Synopsis

A study of the mechanism for N,( B 'II,) deactivation by Nz has been carried out using chemiluminescence in the reaction N(%) +N(?S)( +M)+N,(B 'II., v') +NI(A 3Z:, LJ") +hv. Different NZ isotopes were usedas excited and third-body molecules.

Ni( B.%,, Y) deactivation w& found to involve 15Nz(X 'X:, 02) t "N2(B 31-Ip, vs). electronic energy transfer: '5N2(B311,, o,)+'*N2(X 'Z:, O)+

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