A study of the mechanism for N,( B 'II,) deactivation by Nz has been carried out using chemiluminescence in the reaction N(%) +N(?S)( +M)+N,(B 'II., v') +NI(A 3Z:, LJ") +hv. Different NZ isotopes were usedas excited and third-body molecules. Ni( B.%,, Y) deactivation w& found to involve 15Nz(X 'X:,
Collision-induced electronic deactivation of N2(B3Hg)
β Scribed by B.A. Garetz; J.I. Steinfeld; L.L. Poulsen
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 451 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
We have applied an optical model for potential surface crossing to the clcctronic quenching of N; (l3 "Ilg) by collisons with He, Ar and SF'. Quantitative ngrcement with rcccnt cxpcrimental studies has been obtained.
π SIMILAR VOLUMES
Rate constant calculations for the vibrational deactivation of N2(v = 1) by helium atoms, employing the coupledstates approximation and the potential energy surface of Banks et aI., are presented and compared with experiment in the temperature range 100-300 K. The low impact energy behaviour of the
The collision-induced intramolecular energy transfer N2 (A '2: ) + M+N2 (B 'll,) + M was studied under molecular beam conditions using Xe and Nz as the collision partners. Specifically, the near-resonant transfer between the levels A, VI'= 1 O-B, u'= 2 was investigated by means of the product emissi
## Abstract We have studied the protonated etherβ(H~2~O)~__n__~ (__n__ = 1β3) complexes containing tetrahydrofuran, dimethyl, diethyl, dibutyl, and butylmethyl ethers using a flowing afterglow tripleβquadrupole mass spectrometer. Collisionβinduced dissociation, CID, of all clusters with __n__ = 1,