The mechanism of chain termination in the polymerization of ethylene by a ziegler catalyst
β Scribed by A.F. Rekasheva; L.A. Kiprianova
- Book ID
- 118355237
- Publisher
- Elsevier Science
- Year
- 1962
- Weight
- 232 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0032-3950
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π SIMILAR VOLUMES
A soluble ethylene catalyst were obtained by mixing a methylene dichloride solution of dichlorobislT-cyclopentadienyl) titanium (Cp2TiCI2) with a heptane solution of ethylaluminium sesquichloride (AlzEt3C13) or of diethylaluminium chloride {AIEt2CI). Ethylene was polymerized using these catalysts; t
Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of β£-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of β£-olefins, a high reaction order with respect to ethy