The specific mechanism of chain termination in heterogeneous polymerization
β Scribed by S.Ye. Bresler; M.I. Mosevitskii; I.Ya. Poddubnyi; Shi Guan'I
- Book ID
- 118355483
- Publisher
- Elsevier Science
- Year
- 1962
- Weight
- 545 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0032-3950
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## Abstract The technique of SPPLP EPR, which is singleβpulse pulsedβlaser polymerization (SPPLP) in conjunction with electron paramagnetic resonance (EPR) spectroscopy, is used to carry out a detailed investigation of secondary (chainβend) radical termination of acrylates. Measurements are perform
A~traet A numeric solution is developed for a kinetic scheme involving chain length dependent termination (by disproportionation) and chain transfer on the basis of the harmonic and the geometric mean approximation for the two radicals involved in the termination process. In addition, solutions in t