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The mechanism of autoxidations in alkaline media

✍ Scribed by H.R. Gersmann; H.J.W. Nieuwenhuis; A.F. Bickel


Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
118 KB
Volume
4
Category
Article
ISSN
0040-4039

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The autoxidation of mercaptans in non-aq
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## Abstract The autoxidation of n‐octyl mercaptan and thiophenol in tert‐butanol containing varying amounts of potassium tert. butoxide, yields as the only products disulfide and/or acids (sulfinic and sulfonic). It appears that disulfide is formed from unionized mercaptan, whereas the acids origin