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The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst

✍ Scribed by Abílio J. F. N. Sobral; António M. d'A. Rocha Gonsalves

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
83 KB
Volume
05
Category
Article
ISSN
1088-4246

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✦ Synopsis

The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II.

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